Pretzels – Bicarbonate Applications (2024)

Pretzels are known for their characteristic taste, texture and appearance. Chemical leavening impacts all three characteristics. Sodium bicarbonate is found either in the pretzel dough or in the alkali solution used to dip the pretzels. Ammonium bicarbonate is also used in the pretzel dough to leaven without leaving any residue.

The production steps involved in the manufacturing of pretzels are mixing, fermenting, forming, proofing, cooking, baking and drying. Pretzel doughs are made to be very stiff so that they can withstand the rigors of machining without losing their shape or becoming sticky. The bicarbonates are used to provide an open cell structure within the pretzel.

Of all the steps in the production of pretzels, cooking is the most important. The type of dipping alkali and the proper application of the alkaline cooking solution is the most critical to the taste and appearance of pretzels. An alkaline solution with a high pH will increase the surface browning and flavor contrast. During the bath exposure, natural sugars caramelize and the starch gelatinizes, creating the characteristic brown color and gloss in the finished product.

The dipping stage normally takes just 10-15 seconds of exposure to the hot alkaline solution which is about 200°F. Traditionally the solution was a mixture of sodium hydroxide and water. Today, most production involves the use of sodium carbonate and bicarbonate solutions which are not as caustic as NaOH. Because carbonates and bicarbonates are not as caustic as sodium hydroxide, they are safer to use both in handling and in equipment operation.

Bicarbonate Recommendation

Sodium Bicarbonate Grade 1 Powdered:
Dissolves rapidly to assure quick, complete availability for reaction with acid ingredients.

Sodium Bicarbonate Grade 1 TFF:
Treated with tricalcium phosphate to improve flow quality. Dissolves rapidly to assure quick, complete availability for reaction with the acid ingredients.

Sodium Bicarbonate Grade 2 Fine Granular:
The narrow particle size distribution of Grade 2 facilitates rapid uniform blending. This grade is recommended for those products where minimal leavening during mixing and holding is desired. It is also recommended for products where pre-reaction during preparation can be a problem. It is very useful in refrigerated and frozen doughs to limit pre-reaction with acid ingredients during storage.

Flow K™ Potassium Bicarbonate:
Potassium bicarbonate performs exceptionally well as a replacement for sodium bicarbonate in most chemically leavened products. For equivalent CO2 release, 20% more potassium bicarbonate must be used.

Ammonium Bicarbonate:
ABC reacts rapidly in the presence of moisture and/or heat to release CO2 and NH3 gases which contribute to leavening. Use of ABC without a leavening acid is limited to products whose final moisture is less than 5% so the ammonia gas can bake out.

Pretzels – Bicarbonate Applications (2024)

FAQs

Pretzels – Bicarbonate Applications? ›

The bicarbonates are used to provide an open cell structure within the pretzel. Of all the steps in the production of pretzels, cooking is the most important. The type of dipping alkali and the proper application of the alkaline cooking solution is the most critical to the taste and appearance of pretzels.

What does baking soda do to pretzels? ›

Like lye, baking soda is an alkaline substance, and when mixed with water and brushed over the pretzel dough, it changes the pH of the dough and gelates the surface starch. In the oven, the starch gel hardens and the alkaline baking soda makes browning happen fast.

What does dipping a pretzel in an alkali solution do? ›

An alkaline bath is what makes a pretzel a pretzel and not just a tanned twist of dough. The base reacts with proteins, sugars, and starches at the pretzel's surface to intensify browning and give the skin its tight, glossy sheen. It also imparts that saline, mineral flavor.

What is the alkaline solution for pretzels? ›

Pretzels get their signature dark colour, slightly metallic flavour and chewy-leathery exterior from being dipped in a solution of water and food-grade lye, a strong alkaline ingredient. In the kitchen, baking soda is far more common, but it's a weaker alkali, so doesn't produce quite as dramatic an effect.

Do you bake pretzels with lye or baking soda? ›

Lye is primarily used to make pretzels, and it's the reason for their unmistakable shiny, mahogany color. To prepare, shaped pretzels are dipped in a lye bath, then baked in the oven. This method can also be used with rolls or buns.

Why is ammonium bicarbonate used in pretzels? ›

Ammonium bicarbonate is also used in the pretzel dough to leaven without leaving any residue.

What is the secret solution for Auntie Anne's pretzels? ›

Whisk together 2 cups (454 grams) of warm water and the 1/3 cup (90 grams) baking soda in a shallow dish. Dip the pretzels into the baking soda bath. Flip and dip the other side. Place the dipped pretzels onto a parchment-lined baking sheet.

What is the secret ingredient which makes a pretzel taste like a pretzel? ›

The answer lies in a brief dip in an alkaline water bath before baking. This bath essentially gelatinizes the outside of the pretzel, preventing it from fully “springing” during baking (as bread does) and giving pretzels their signature chewy crust. It also gives them their unique and indelible “pretzel” flavor.

Is lye in pretzels bad for your stomach? ›

Basically, the lye reacts with the CO₂ and moisture present during baking to form a non-toxic carbonate. This makes it safe to eat.

What chemical do you dip pretzels in? ›

Most bakers use food-grade lye, which is the chemical equivalent of drain cleaner, but is produced and packaged in a clean, regulated way. Since the lye dip is heavily diluted and the pretzel is baked after dipping, it won't kill you.

What pH should pretzels be? ›

These days, most recipes call for using baking soda (9 on the pH scale), but traditionally, pretzels were glazed with lye, which has a pH level of 14! Boiling dough also gives it its shiny appearance.

How do you dilute lye for pretzels? ›

To prepare a lye bath for pretzels, fill a large liquid measuring cup with four cups of cold water. Add the water to a heavy, plastic container and carefully mix with two tablespoons of food-grade lye until fully dissolved.

What does bicarb do to pretzels? ›

As noted above, baking soda is a staple ingredient for making homemade pretzels. Dunking your pretzels in a baking soda bath prior to baking is what enables them to develop their distinctive color and crispy-on-the-outside, chewy-on-the-inside texture.

Does Auntie Anne's use lye? ›

Well, the cheery ladies were very clear with me: they do NOT use lye. No sodium hydroxide/poison/caustic soda—none whatsoever—in their pretzels. (They do, however, dip their pretzels in a baking soda solution.) So there you have it.

Why do you dunk pretzels in baking soda? ›

Furthermore, we've introduced the baking soda bath. While it sounds strange, this step is what gives pretzels that iconic flavor, chewy texture, helps deepen their golden color in the oven, and locks in the super soft interior.

Can you skip the baking soda bath for pretzels? ›

The boiling water also locks in the shape so the pretzels don't over-puff in the oven. (Without the baking soda bath, you lose texture, that deep brown color, and flavor. So, basically, you will have bite-size bread instead of pretzels.)

Does baking soda help crisp? ›

Is baking soda or powder best for frying? A pinch of baking soda can help produce crispy fried foods. It reacts with the acid in the batter to create carbon dioxide bubbles. These lead to an airy batter and a crisper, fluffier result.

Does Auntie Anne's use baking soda? ›

Before any Auntie Anne's pretzel goes into the oven, it's brushed with their special solution of warm water and baking soda.

Why are my homemade pretzels so dense? ›

Baking Tips

Let the dough rest before you shape it. If you don't let the dough rest, you run the risk of over working it, which would result in tough, dense pretzels. Don't omit the sugar from the recipe.

References

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